Determination of thinner content of paint and coating by gas chromatography

Thinner is an important part of paint, and it plays a very important role in the manufacture and storage of paint, the formation of paint film and its durability. For this reason, Nanjing Kejie applies gas chromatography technology to the composition detection of paint thinner. After the paint thinner is completely evaporated, it will inevitably cause pollution to the environment and indoor air. Consumers often do not know how to choose environmentally friendly paint. Therefore, it is very valuable to analyze and determine the content of the paint thinner component, not only for enterprises Technical reference to provide useful guidance for consumers to choose true environmentally friendly green paint solvents.

1. Gas Chromatograph Detecting Diluent Instruments and Reagents

GC-5890 gas chromatograph hydrogen flame ion detector (FID),

GX-300A Nitrogen, hydrogen, and air all-in-one machine or (one for nitrogen, hydrogen, and empty cylinder)

The main components of paint thinner: benzene, toluene, methanol, isopropanol, isobutanol, n-butanol, acetone, n-butanone, methyl isobutyl ketone, cyclohexanone, ethyl acetate, ethylene glycol butyl Ether, xylene, trimethylbenzene, 120 # gasoline is the solvent for industrial production of paint and coating enterprises

Technical parameters of GC-5890F gas chromatograph

1. Temperature control

Temperature control range: 7 ℃ ~ 400 ℃ at room temperature (increment 0.1 ℃)

Cheng Sheng degree: third order

Ascent rate: 0.1 ℃ ~ 50 ℃ / min (increment 0.1 ℃)

2. Detector FID

Detection limit: ≤5 × 10-12g / s (n-hexadecane)

Baseline noise: ≤6 × 10-12A / H

Linear range: ≥105

Stabilization time: <20min

3. Detector TCD

Sensitivity: ≥10000mV? Ml / mg (n-hexadecane)

Baseline noise: ≤30uV (Carrier gas is 99.999 hydrogen)

Second, the purpose of the experiment

Gas chromatography analysis technology has the advantages of high separation efficiency, fast analysis speed and good selectivity, and has been widely used. Most of the reasons for paint thinner problems are due to formulation problems. Through gas chromatography, the composition of paint thinners is analyzed, and the composition of paint thinner formulas used for similar substrates with different properties is compared and analyzed. Provide guidance for various unfavorable problems in construction, and solve practical technical problems for enterprises. In most cases, the price of ethanol is much lower than that of butyl acetate. Adding a small amount of n-butanol to alkyd resin paint can significantly reduce the viscosity; adding a small amount of isobutanol to the paint can effectively prevent the paint film from whitening, and can also improve the fluidity and gloss. The amount of diluent added can be controlled by gas chromatography, and it can also be used to identify benzene, toluene and other benzene series solvents that are more toxic in the paint, providing useful guidance for consumers to choose true environmentally friendly green paint solvents. Water-soluble electrophoretic paint It is a kind of paint developed in the 1960s. Isopropyl alcohol, n-butanol and ethylene glycol monobutyl ether are all effective ingredients added in the solvent of water-soluble electrophoretic paint. Its content affects the use effect and economic cost of electrophoretic paint. Among them, ethylene glycol monobutyl ether is a high-boiling solvent in electrophoretic paint, used as a dispersant and wetting agent. When the gas chromatography method is used for detection, it has simple operation, accurate quantification, fast analysis speed, and accurate results can be obtained by one injection.

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